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spread of different environmental media, together with the environment, floor waters, groundwaters and soil (Fig. four. The variety of biological pollution is actually unquantifiable. They include not solely residing and viable organisms, similar to micro organism, but additionally the huge array of endotoxins that can be released from the protoplasm of organisms after dying. There is, subsequently, no scarcity of potential environmental dangers to health. What is missing, for essentially the most half, is an understanding of the character and mechanisms of these risks. Secondary natural aerosol is fashioned in the atmosphere when volatile natural compounds emitted from anthropogenic and biogenic sources are oxidized by reactions with OH radicals, O, NO radicals, or Cl atoms to form much less volatile merchandise that subsequently partition into aerosol particles. Once in particles, these natural compounds can bear heterogenous/multiphase reactions to kind more extremely oxidized or oligomeric products. SOA contains a large fraction of atmospheric aerosol mass and may have vital effects on atmospheric chemistry, visibility, human health, and local weather. Previous articles have reviewed the kinetics, merchandise, and mechanisms of atmospheric VOC reactions and the final chemistry and physics concerned in SOA formation. In this article we current an in depth evaluation of VOC and heterogeneous/multiphase chemistry as they apply to SOA formation, with a focus on the consequences of VOC molecular construction on the kinetics of initial reactions with the main atmospheric oxidants, the next reactions of alkyl, alkyl peroxy, and alkoxy radical intermediates, and the composition of the resulting products. Structural options of reactants and merchandise discussed embrace compound carbon number; linear, branched, and cyclic configurations; the presence of C[double bond, size as m-dash]C bonds and aromatic rings; and practical teams such as carbonyl, hydroxyl, ester, hydroxperoxy, carboxyl, peroxycarboxyl, nitrate, and peroxynitrate. The intention of this review is to provide atmospheric chemists with sufficient info to grasp the dominant pathways by which the major classes of atmospheric VOCs react to form SOA products, and the further reactions of these merchandise in particles. This will

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